The reactivity and properties of polyoxometalates (POMs) vary remarkably as a function of the kind of addenda atoms, so the design and synthesis of new mixed-addenda POMs is a promising approach for the further development of the POM-related areas. In the present work, the first Mo/Ta/W ternary mixed-addenda POM (NH₄)₄₁H₇[K₃(H₂O)₃(P₂W₁₅Ta₃O₆₂)₆(Mo₂O₄CH₃CO₂)₃(MoO₃)₂]·85H₂O (1), which is composed of 6 {P₂W₁₅Ta₃O₆₂} linked by 3 {Mo^V₂O₄(OOCCH₃)⁺} and 2 {Mo^VIO₃} via 18 novel Mo–O–Ta bridges has been synthesized. The precursor {P₂W₁₅Ta₃}, which has lower redox potential, is crucial for the formation of 1. The red-brown solid sample of 1 shows strong absorption in the visible region. The visible-light responsive charge transfer from benzylamine to 1 was observed experimentally. 1 was proved to be an efficient photocatalyst under simulated sunlight (AM 1.5G) radiation for the oxidative coupling of primary amines to imines using atmospheric O₂.

链接地址：https://doi.org/10.1021/acsami.9b16694