祝贺荆怡同学的论文在Inorganic Chemistry上发表
更新时间:2022-09-09
题目:Synthesis, Formation Mechanism, and Structure of K[BH3S(CH3)BH3] and Its Application in Preparation of KB3H8
【返回列表页】 作者:Xi-Meng Chen, Yi Jing, Jia-Xin Kang, Na Zhang, Chen Zhang, Xin Jiang, and Xuenian Chen*
摘要:The design, synthesis, and applications of new boranes are eternal topics in boron chemistry. A new bis(borane)alkanethiolate salt, K[BH3S(CH3)BH3], was synthesized in high yield by the reaction of K with (CH3)2S·BH3 at room temperature. The formation mechanism was elucidated based on experimental and theoretical studies. The single-crystal structure of the K[BH3S(CH3)BH3]·18-crown-6 adduct was determined in which the B−S−B bonding information of K[BH3S(CH3)BH3] was illustrated for the first time. Using K[BH3S(CH3)BH3] as a starting material, KB3H8 was successfully synthesized.
DOI:10.1021/acs.inorgchem.2c01912