祝贺彭青坡同学的文章在Dalton Transactions上发表
更新时间：2017-02-27
Lanthanide derivatives of Ta/W mixed-addendum POMs as proton-conducting materials
Qingpo Peng, Shujun Li, Ruoya Wang, Jianxin Zhai, Shuxia Liu, Jie Zhang, Qianyi Zhao and Xuenian Chen
Dalton Trans., 2017, DOI: 10.1039/C7DT00091J
Four Lanthanide derivatives of Ta-containing POMs [Ln3(H2O)22][P2W15Ta3O62]•nH2O (Ln= La , 1; Ce, 2; Pr, 3; and Nd, 4) were isolated by the self-assembly of well-Dawson type Ta/W mixed-addendum POM and lanthanide ions. Compound 1 showed excellent proton conduction performance at high relative humidities (RHs), with conductivity reached to 1.26 ×10-2 S•cm-1 at 95 °C under 98% of RH.
http://pubs.rsc.org/en/content/articlepdf/2017/dt/c7dt00091j