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祝贺陈学年老师和李慧珍老师参编的"HANDBOOK OF BORON SCIENCE"顺利出版!

更新时间:2018-09-28

该套丛书共有4卷,详细论述了硼在金属有机、催化、材料及医药领域的应用研究成果。
陈学年老师和李慧珍老师编写的内容如下:
Chapter 1 Small Amine Boranes
1. Introduction
2. Structures
  2.1. Structure of AB
  2.2. Structure of DADB
  2.3. Structure of ADB (NH2B2H5)
  2.4. Structure of DDAB
3. Syntheses
  3.1. Syntheses of AB
    3.1.1. Metathesis Reaction
    3.1.2. Displacement Reaction
    3.1.3. Decomposition of DADB
  3.2. Synthesis of DADB
    3.2.1. Reaction of B2H6 with NH3
    3.2.2. Reaction of NH4+ with BH4-
    3.2.3. Reaction of [NH3BH2NH3]+ with BH4-
  3.3. Synthesis of ADB
  3.4. Synthesis of DDAB (NH3BH2NH2BH3)
4. Formation Mechanism of AB, DADB and ADB
  4.1. Formation Mechanism of AB and DADB
    4.1.1. Formation Mechanism of AB and DADB from the Reaction of B2H6 and NH3
    4.1.2. Formation Mechanism of AB and DADB from THF · BH3 and NH3
    4.1.3. Formation Mechanism of AB and DADB from NH4BH4
  4.2. Formation Mechanism of ADB from THF · BH3 and NH3 · BH3
5. Roles of DHBs in Amine Boranes
  5.1. General View of DHBs
  5.2. DHBs' Effects on Physical Properties and Structure of Amine Boranes
  5.3. DHBs' Effects on Reaction of Amine Boranes
    5.3.1. DHBs' Effects on the Intermediate of Formation Mechanism of Amine Boranes
    5.3.2. DHBs' Effects on Proton Transfer/Exchange
    5.3.3. Synthesis of New Amine Boranes and Other Materials



 
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